Typical military survival kits usually have a vial of potassium permanganate. It can be used to purify water in dilute solutions, as a disinfectant when used in concentrated solutions and a marker for signaling in snow. But, it can serve one more purpose that of a firestarter. When a fine granules of potassium permanganate are rubbed with sugar or glycerine the result is an exothermic reaction. Using it in an actual survival situation, I reckon are slim. If you have access to potassium permanganate in a survival situation. It is most likely that it is, because, it was part of a survival kit. In that case you definitely have other more convenient means of starting a fire. But, sometimes just knowing a possibility exists can be a lifesaver.
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